Category: Chemistry

Why is Orange Juice + Toothpaste the Worst Idea

If you are one of those people who like to have orange juice in the morning just after they have brushed their teeth, you probably know how bad that tastes. Drinking orange juice after brushing your teeth brings about a very repulsive taste in the mouth. If you haven’t tried that, try it once. Trust me, toothpaste + orange tastes awful.

Water, fluoride, detergent and abrasives are the four major components of toothpaste. And the most common detergent (used to form foam) is called Sodium Lauryl Sulphate, or SLS. SLS has some strange effects on your taste receptors. It suppresses the receptors which help you taste sweet

Also, it destroys a compound called phospholipid – compounds meant to suppress the bitter taste. These are the two accepted reasons as to why drinking orange juice after brushing your teeth is probably a bad idea.

Screaming Coin and a Singing Spoon

By Anupum Pant

Dry ice, or Cardice – as British researchers call it, is a solid form of carbon dioxide. When carbon dioxide is cooled below temperatures of -78.5 degrees centigrade, the gas gets directly frozen into a solid form. -78.5 degrees centigrade is extremely cold, and handling dry ice without proper protection can be very dangerous – could cause frostbite / burns. The point being, it’s extremely cold.

Since it’s too cold compared to something at room temperature, even everyday objects at room temperature can make it vaporize. A simple metal coin at room temperature would feel like a hot pan to dry ice. So, when a coin is shoved into a piece of dry ice, it creates a funny sound, just like water would, on a very hot pan; or, you could say the sound be very much like a hot metal ball being dropped into a cold bath of water (the temperature difference being much less in this case, of course).

This is how it works: The metal piece at room temperature vaporizes some amount of carbon dioxide from the piece of dry ice when it comes in contact. There’s a pressure difference (Bernoulli’s principle) associated with this process and the gas tries to escape. This makes the metal vibrate very fast, creating that funny sound. This is how it sounds…

Metals work best because they have a good thermal conductivity. For the sake of trying it out yourself, if you have a piece of dry ice lying unused, you could dip a spoon in hot water and make it touch the piece of dry ice. A slightly warmer spoon will probably give you a better effect. And then the spoon will be singing…

Nanokids and Nanoprofessionals

By Anupum Pant

In the year 2003, a group of researchers headed by James Tour at Rice university designed and synthesized a series of organic molecules that they thought would get kids interested in chemistry.

These organic molecules resembled human figures and were named Nanoputians – A portmanteau of nanometer (a unit of length used to measure extremely tiny distances) and Lilliputian (the tiny human-like fictional characters from Gulliver’s travels).

The synthesized nanokid molecule basically consisted of two benzene rings and a couple of carbon atoms for its body. For the limbs  acetylene units ending in an alkyl group were used. The upper body and the lower part were both created separately, and were joined using Palladium and Copper compounds. Here’s how…

nanokid body parts

The head of a basic Nanoputian was a 1,3-dioxolane ring. However, after using an advanced microwave irradiation technique, the team created a couple of other variants (called Nanoprofessionals) to replace the Nanokid’s head. Here is what the series of head variants that were created. As if that wasn’t enough, there is a nano ballet dancer too.

nanokids and nanoprofessionals

Now, in the scientific community, James and his team are better known for synthesizing a much more cooler thing – A nanocar. The nanocar they synthesized was a single molecule car which could be pushed around using a scanning tunnelling microscope. And another one which is fuelled by light!

There are a couple of other cool molecular machines they’ve made too.

via [FutilityCloset]

The Landolt Clock Reaction

By Anupum Pant

Steve Spangler Never ceases to amaze me. Once again I found this old video of him on the Ellen show. These are a few experiments he does on the stage…

  • Lights a tube light with his bare hands and Ellen’s.
  • A transparent liquid suddenly instantly changes colour.
  • Blows the hydrogen and oxygen mixture on Ellen’s hand.
  • And makes someone from the audience walk across the table on a non newtonian fluid.

Steve doesn’t exactly explains what happens there, but the second experiment is my favourite. It is the one in which he asks Ellen to pour two transparent liquids into each other and mix them well. Then Ellen waits for a few seconds and the liquid instantly turns into an ink like colour.

The magical effect is actually a chemical reaction known as the Landolt Clock Reaction. It actually involves 3 different solutions (read about them). The reaction happens quicker once the mixing starts and leads to a third reaction which happens immeasurably fast. It’s totally instantaneous and thus the transparent solutions turn into a bluish black iodine starch complex. As steve’s website puts it…

The sudden change from a colorless solution to the blue-black solution is the result of four sequential reactions. First, the bisulfite ions (HSO3-) reduce some of the iodate ions (IO3-) to form iodide ions (I-). Next, the iodide ions (I-) are oxidized by the remaining iodate ions (IO3-) to form triiodide ions (I3-). The solution now consists of triiodide ions (I3-) and soluble starch. In the third reaction, the triiodide ions (I3-) get reduced by the bisulfite ions (HSO3-) to become iodide ions (I-). That continues until all of the bisulfite has been consumed. Finally, the triiodide ions and starch combine to form the dark blue-black starch complex that looks like ink.

See more at: SteveSpanglerScience

Brass Doorknobs of Public Restrooms

By Anupum Pant

I remember my grandma telling me to keep some water overnight in a copper pot, and in the morning, she used to drink it. I never understood why she did that. Backed by solid science, today I’m able to appreciate her age-old wisdom.

Today, to get rid of the problem causing bacteria, trusting brass doorknobs is better than trusting those triclosan lad anti-bacterial soaps. Yes, brass can kill bacteria very effectively.

Doorknobs are probably the most touched objects, especially the ones that are on the doors of a toilet at the mall. A doorknob probably even beats smartphones because a doorknob is accessible to anyone and everyone, whereas a smartphone is usually touched by a single individual.

Although, I’m not totally sure that a doorknob is really one of the most touched objects, one thing is for sure – Door knobs are the places where an incredible amount of sickness causing germs get collected. Thanks to the thousands of unclean hands coming straight from the toilet and touching the knob for the day.

And yet, you don’t often get sick after touching public restroom knobs. That is because doorknobs are normally made of brass. Brass and a couple of other metals have an ability to clean themselves – in a given amount of time these metals are able to sterilize themselves! This is called the Oligodynamic effect. Sounds like a cool name to remember because it’s easy to remember and nothing else would annoy your friends more than you bringing it up amidst conversations…

It has been tested and found that brass is able to sterilize itself in the span of eight hours. While some have tried to explain how it works, no one has been able to explain the effect in a satisfactory manner.

Other metals like silver, copper and copper alloys are able to kill bacteria better. Silver, purportedly is a very robust disinfectant. But, not many would be able to afford doorknobs made out of silver or pure copper. Instead, a far cheaper alloy consisting of copper and zinc (brass) is used to make bacteria zapping doorknobs.

Stainless steel and aluminium metals aren’t able to do this. Be careful when you have to twist doorknobs made of Steel or Aluminium. These are metals that could get you sick.

[Wikipedia]

Superfluid Helium is One Strange Liquid

By Anupum Pant

Helium can’t be frozen into a solid (at atmospheric pressure) – the very property which allows it to go from a simple liquid Helium state (warmer) at minus 269 degree C – where its boiling and evaporating quickly – to a much calmer Liquid Helium II stage (cooler).

Liquid Helium  II is obtained at a temperature lower than minus 269 degree C, at about minus 271 degree C – known as the Lambda point.

Liquid Helium II is a superfluid. Superfluid Helium has no viscosity. It behaves extraordinarily. As a summary of how extraordinary superfluid Helium is, here is a list of things it can do:

  • Superfluid Helium will leak out of solid ceramic containers which have extremely tiny pores that no other liquid can penetrate.
  • If it is taken in a container and the container is spun around the central axis, the superfluid will not spin.
  • Somehow if you manage to spin it, because it has no friction, it won’t stop.
  • It can climb walls of a container by forming an extremely thin film and defying gravity.
  • It can produce an eternal frictionless fountain.
  • It can conduct electricity better than some of the best metal conductors like Copper! It’s a big thing for a liquid to be able to do that.

Here is a summary video you can watch below.

But, I’d suggest watching the whole documentary here. It explains everything that superfluid helium can do in nice detail. Also, the researcher makes sure it is in a very simple language…

Spicy Food for a Happy Stress Free Life

By Anupum Pant

Today I’d like to start with something called Morphine. There is great chance that you already know about Morphine, may be through House MD, or other things. If you do, you could skip if you want to. But reading through a couple of lines never hurt anybody.

Morphine: is one of the most effective drugs used in medicine to relieve severe pain. It acts directly on the central nervous system, relieves anxiety and produces euphoria – intense happiness. That is the reason, it is also widely used illegally as a recreational drug. Wait! It is highly addictive too. But what makes me talk about morphine today?

Endorphins: And then there are Endorphins. Endorphins, short for Endogenous Morphine, is a morphine like substance made by the body – Where endogenous means that it originates inside the body. The amount of it released in the body is completely dependant on how you live your life and the kind of food you eat.

Like morphine, Endorphins have some function in the body too. In simple words, they relieve pain and stress. For instance, in a body builder’s body, these are the natural chemicals which keep them going in the gym, by mitigating pain sensation. And of course, since it is nothing but Morphine occurring naturally in the body, it creates Euphoria, or a state of intense happiness.

Runner’s High: People who are engaged in strenuous activities often have high amounts of Endorphins being released inside their body. As a result, they develop something called a runner’s high – An addiction to exercise and other strenuous activities. May be this is how workaholics are born. I’m guessing, endorphins is the chemical that gives the Tarahumara people the ability to run for 400 miles. And may be Marathon Monks of Japan also have unlocked a technique to produce high amounts of Endorphins in them (meditation!).

Whatever it is, healthy amounts of Endorphins released in the body make you happy, and a greater amount than that only takes you to a super human level. Of course, using morphine without prescription is not legal. But, there’s no law that can stop you from creating it in your own body. After all, it can completely change you as a person.

How to: Now, there are a couple of natural ways you could train your body to make more of it for you. Some of them are – strenuous exercise, a lot of sleep, eating chocolate and meditation (marathon monks!). But, among these techniques, in my view, adopting excessively spicy food is the most accessible and healthy way to go about it. Heck, just eat chillies and be happier. So simple. If you think that is hard, well, the human body can easily be trained…

Among scientists, it is a well-known fact that eating chilli peppers can lead to enhanced secretion of endorphins. It is also noteworthy that spicier the chilli, more endorphins are released. And to find the spiciest chillies, you can probably watch the video below…

So, go, rev it up to 16 Million Scoville Scale unit and lead a happier and stress free life. Use science and get addicted to happiness.

Note: Do whatever, but do not over do it. You don’t want to try the deadly cinnamon challenge to be happy.

Aluminium Used to be Costlier than Gold

By Anupum Pant

Unlike gold and silver, there is enough Aluminum in the world. It is in fact, the third most abundant element in the Earth’s crust. Also, it is about two times more abundant than Iron – an element which has a complete  branch of metallurgy revolving around it – Abundance of Aluminium is 2 times of that! Still, for the middle class of the 19th century, bricks made of Aluminium were things they could only dream to buy – Aluminium costed more than gold back then.

The same metal, Aluminium, certainly shines like silver. But our generation almost has no respect for it. Today, it is one of those blasé metals that is used to make disposable soda cans.

Back then, the US, to show off its wealth, decided to cap the Washington monument with a 3 kg pyramid of Aluminium. Later, since enterprising individuals found out a way to extract it in a very efficient manner, Aluminium became something that was not all that rare. People in the 19th century knew how precious it was. That was because, back then there was no good way to extract aluminium from its ore.

In the 19th century Napoleon III invited the King Siam to a dinner. He then gave himself Gold Cutlery, his troops Silver & the King of Siam Aluminium. This was no insult but an honour because aluminium was the most valuable metal on the planet at that time. Today, aluminium is $1,800 a ton while Gold is $50 million. – [Source]

In the mid-1800s, an Aluminum ingot would sell for about $550 per pound. Fifty years later, it costed around 25 cents for the same amount. What changed? Extraction.

The Evil Powdered Alcohol or Palcohol

By Anupum Pant

As if liquid alcohol wasn’t itself causing enough menace, now we have this futuristic powdered alcohol. They call it “Palcohol”.

All you need is, to mix a little of it with water, and there, you have your doze for the day. Other way to consume it would be to snort it for an “instantaneous high”, which by the way, is nothing less than deadly.

On an unrelated note, I find the host of this show is so adorable.

Problems

  • Palcohol certainly makes it easy for kids (and others) to carry alcohol around, and also to move it into places where it isn’t allowed (football games and concerts), which is definitely not desirable.
  • Also, the powder is highly flammable. Who wants a bomb in their pocket?
  • Another really bad thing about it is that it can easily kill you. Snorting can damage your mucous membrane. Also, since it is alcohol in high concentration, you can easily overdose on powdered alcohol and pass out.
  • The nightmare of every person, date rape, well, that just got a lot easier. Scary! How easy would it be for a creep to slip this powder into a drink of an unsuspecting victim – This is also Lacy’s primary concern (watch the video below).
  • So many new laws need to be in place before it gets available for public.

The patent to create powdered alcohol was published long back, in the 70s, but it is only now that they have got a federal approval. However, the Fed’s approval was taken back due to some issues. It is interesting to note that several other countries like Japan, Netherlands and Germany already have such products that are being sold in the market. How do the authorities in those countries  deal with this menace!

Nevertheless, Palcohol, a new and improved way to get drunk is here. It’s not going back.

Good news (?) is that it can be made at home. Read this PopSci article for the recipe.

I see only problems with Palcohol. I don’t think it needs to be in the retail market. What do you say?

Is Helium Beer Possible?

By Anupum Pant

Background

For the fizz, almost all beers have carbon dioxide dissolved in them. However, some others have also experimented with Nitrogen beers. But as fas as I know, no other gases have been used to make beers. Tell me in the comments section if you know any other gasses that have been used to do this.

But, on April 1st  Samuel Adams announced a Helium beer on his YouTube Channel. Note, the date was 1st  April. Here is the video of the announcement.

Save Helium and Science of the Fake Beer

Of course it was an April fools stunt. But what if it was real?

In his “HeliYum beer” Adam announced that, instead of carbon dioxide to create the fizz, he had used the Helium gas in the beer. In the video, as an additional effect, the new beer gas also created a funny atmosphere by affecting the voice of beer tasters. Now, I certainly didn’t like the idea of using Helium to keg beers because I’m very touchy when it comes to wasting the precious gas – Helium. Why? Well, read this Helium article I wrote some time back.

Also, I was adamant in believing if it was even possible to do that. Firstly, the date was 1st  April. Secondly, the science clearly didn’t allow this. Here’s why…

1. Helium is about 700 times less soluble in water as compared to carbon dioxide. It is one of the least soluble gases in water and only about 0.0016 g of Helium would get dissolved in a litre of beer. While, at the same conditions, 2.5 g of carbon dioxide is usually present in a litre of beer. This dissolved carbon dioxide is what realeases slowly and creates the fizz. No slow fizz can be done with Helium. Undissolved helium in beer would coalesce into one or two big bubble and…ploop, would go out as soon as the seal would break.

2. Even if Helium was forced into the beer and sealed in a beer can, it would be useless. As soon as the seal would break, all the meaningful amount of helium present inside, undissolved, under pressure, would come out so quickly (due to less viscous beer) that it would bring out a lot of beer with it. It would create a mess. And you wouldn’t be able to even bring the can near your face by the time the whole gas goes away.

Had carbon dioxide been used for the same purpose, the gas would, like it normally does, come out steadily. It would make the bubbles last.

Verdict: No. It’s useless to try to make beer with Helium unless you make it so viscous that it won’t let the Helium pass so easily. In that case, it won’t be beer really. Also, I’m not sure if the fermentation process could take place in such a viscous condition.

Donating = Loving


A small donation worth a single cup of coffee from you can be the difference between this website existing or not. If you like this, please consider buying me a cup of coffee:

5 Visually Incredible Science Experiments You Cannot Miss

By Anupum Pant

Here is a small list of visually incredible science experiments that will keep you visually mesmerized for a couple of minutes. Later, you’ll be left wondering about what you just saw.

The list is a small one, to not overwhelm those avid readers who follow the articles everyday. I think, more than 5 videos, is just too much wonder to take for a single day.
I do have a collection of hundreds of other such incredible experiment videos (in my bookmarks) that I’ll be sharing in the future…probably with the same heading suffixed with “part 2”.

Now without any more delay, here is the list. Have fun and do share if you like them! Ask me in the comments section if you have any questions.

1. Decomposition of Mercury (II) Thiocyanate

2. Liquid Nitrogen + 1500 Ping Pong balls

3. Dry Ice + Water

4. Quantum Trapping / Quantum Locking

5. Flying top

Harmless Flour is an Incredibly Explosive Substance

By Anupum Pant

Background

The next time you are biting off from a bread, pizza, pancake or a doughnut, you should probably take a minute and pay a silent acknowledgement to the people who work in flour mills to bring flour to your homes. Yes, because flour, the seemingly harmless cooking ingredient can be an incredibly dangerous substance – It explodes.

Wait a minute. It isn’t a minor explosion I’m talking about. I’m talking about really big explosions. Read on to know more.

Burning Flour

Flour is almost completely starch (or carbohydrate). Since Carbohydrate is nothing but a large molecule which is essentially a couple of sugar molecules linked to each other, it burns like sugar. And everybody who has tried burning marshmallows on a candle knows how easily sugar catches fire. Agreed, carbohydrate isn’t as sweet, but it is just like its cousin sugar when it comes to flammability.

So, that is how flour can catch fire. But what is it that makes it bring down full-sized buildings?

Flour in air

Flour in your kitchen’s flour container can be a very boring thing. The fun starts when the tiny flour particles are suspended in air.

Flour particles suspended in air, or for that matter, almost anything suspended in air that can catch fire, is a dangerous thing. For example, look at one of the most hazardous situation you can have in a coal mine – There is coal dust around and accidentally there is a small sparkle around it. The whole place explodes like a bomb. This has resulted in some of the worst ever mining accidents in the history.

Such explosions happen because anything that is in powdered form and is suspended in air, has a far more surface area exposed to oxygen per unit weight, than normal lumps of the same substance. This is true for industrial stuff like powdered coal, sawdust, and magnesium. Besides that, mundane substances can explode too – like  grain, flour, sugar, powdered milk and pollen.

All it takes to cause a disaster is a suspended combustible powder and a little electric arc formed from electrostatic discharge, friction or even hot surfaces – A little spark is enough.

Such settings are common in flour mills, where there is flour floating around literally everywhere. This is what caused a giant explosion in a flour mill in Minnesota on May 2nd, 1878, killing 18 workers. But that was more than 100 years ago. Kitchens are relatively safe because you don’t have enough flour in the air to catch fire and produce great volumes of air that are enough to cause an explosion.

This happens even today. From the year 1994 to the year 2003 there have been 115 such reported explosions in food processing industries in the US.

[Source 1] [Source 2] [Source 3]

Experiment

The following is a simple experiment you can do at home (obviously with adult supervision) to understand the explosive nature of a harmless cooking ingredient. [Video]

What you need: Safety glasses, Tin can (with lid), Candle, Matches, a long Straw and fine white flour

  • Take a tin can, one with a relatively tighter lid. Make a hole at the lowest point in the side wall (just enough to fit in a straw).
  • Open it up and put in a handful of flour inside it. Now is the time to put on your safety glasses.
  • Now, burn a candle and carefully place it inside the can.
  • Close the lid, insert the straw into the hole. Now blow at the base of the can, in a way that flour stirs up inside without extinguishing the candle.
  • Watch the lid pop up 10 feet into the air.

Making Glow Sticks at Home is Fairly Easy

By Anupum Pant

Glow sticks or Light Sticks are so much fun and assuming you are able to get the required chemicals from a lab supply shop (online or offline), making them at home is as simple as mixing tang.
I came across this interesting video which teaches you how to make glow sticks at home. The best thing: You don’t have to worry about mixing exact measurements. An experiment definitely worth a try!

As the video tells you in the beginning, making these at home will cost you more than a ready-made glow stick. That is because the chemicals required to make it cost much lesser when bought in bulk. Nevertheless, it should be fun to try at home. If you can’t watch it, I’ve mentioned everything in detail below. [video]

1. SOLVENT: The first thing you need is Diethyl Phthalate (DEP). It is a fairly common substance because it is used a lot in detergent, sprays, cosmetics industries. Although it is clear and looks almost like water, you should avoid touching it with bare skin. In fact, none of these chemicals should be touched. Gloves are extremely important here. DEP will be your main solvent. All the magic will happen in it.

2. COLORS: The second part of making glow sticks involves the color. For this, you’ll need something called the fluorescent dyes. The ones used in the video are:

  • 9,10-bis(phenylethynyl)anthracene for Green – Orange in solid state.
  • Rubrene for Yellow – Red in solid state.
  • 9,10-diphenylanthracene for Blue – White in solid state.
  • and Rhodamine B for Red – Green in solid state.
  • Mix the blue and Yellow solutions for the white glow stick.

3. ENERGY: To make enough energy to light it up you’ll need a mixture of three chemicals. The first one is TCPO (DNPO or CPPO can also be used). It is an expensive chemical. It can be made for much cheaper [video]
The second chemical is added to keep the liquid in alkaline state. Sodium Acetate (Remember Hot Ice).
In the end, you add, Hydrogen peroxide and shake to give the final glow. It acts as an oxidizing agent, reacts to form an unstable compound, which excites the dye to an excited state. The dye emits light when it comes back to the ground state. This is the reason you need Fluorescent dyes – normal dyes won’t work.

For more of such interesting chemistry tricks do subscribe to NurdRage on Youtube.

To make a permanent Glow Stick

Related articles
Enhanced by Zemanta

Make Your Voice Sound Like a Cowboy (Girls Also)

By Anupum Pant

Everyone who watches The Big Bang Theory on TV must have had a hearty laugh when Sheldon’s voice went funny in the 9th episode of season 3 (video).
In the video, when Sheldon starts talking on an NPR show about magnetic monopoles , Kripke uses a Helium tank to fill Sheldon’s room with Helium. As a result, his [Sheldon’s] voice shifts pitch and starts sounding really funny.

In this article we’ll see, what is it in Helium that makes our voices go funny. And we’ll also see another interesting gas that makes your voice sound like a cowboy. But first, some things about Helium:

Helium Warning

1. Do not use Helium to play. It is kind of a non-renewable resource. At the same time, it is used in laboratories for physics experiments. When you play with it and release it into the atmosphere, Helium is lost forever. I wrote an article on this couple of days back. [Understanding the impending Helium crisis]

2. Although Helium is a non-toxic gas and no it doesn’t kill brain cells, it can still kill you. Pranks like the one Kripke uses, which could potentially fill up the whole room with Helium could have lethal consequences. Too much Helium and you’ll not be breathing [enough] Oxygen. Even if you don’t care about the first point, you should think about inhaling more than 3 Helium filled balloons (or any other gas) during parties – it could kill you by asphyxiation (specifically, Hypoxia).

Talking about death, these speakers can also kill you – Plasma Speakers.

Why does Helium make voices go Daffy duck?

Helium is the second lightest element (gas) after Hydrogen. It is six times lighter than air. And if you’ve read this article on how sound works, you probably know that sound travels with different speeds through different mediums.
The speed of sound is about 3 times faster in helium, than in air. When you take in Helium, it increases the speed of sound that comes out of your mouth. It does nothing to your vocal chords. Faster sound and same wavelength results in a higher frequency sound.

Contrary to what is popularly believed, Helium doesn’t technically alters the pitch of your voice. [Read more]

Sulphur Hexafluoride

Helium voices are quite popular. On the other hand, sulphur Hexafluoride voices aren’t very commonly known.
Completely opposite to Helium, this is 6 times heavier than air. So, inhaling it makes your voice go really deep. The mechanism is just opposite to that of Helium. It makes sound move slower. Again, technically, it doesn’t change the pitch of your voice. Watch the video below:

Where can you find this gas?

Sulfur hexafluoride is used for eye surgery and ultrasound in hospitals. Also, it is widely used in the industry for various things. So, you could go to someone, who supplies gasses like these (Oxygen, Argon etc.) to hospitals and industries. Then you could request them to let you collect it in a small balloon (they won’t let you).
So, you could simply study science, work in laboratories and have such fun activities everyday (in moderation).

Side Note: Inhaling another non-toxic noble gas, Xenon, also does something similar. It is heavier than air so it makes your voice deep. At the same time, xenon will make your pockets extremely light.

Related articles
Enhanced by Zemanta